由电子探针分析数据估算角闪石、黑云母中的Fe~（3＋）、Fe~（2＋）     

林文蔚  彭丽君 《吉林大学学报(地球科学版)》1994,(2)

待定矿物化学式中阳离子数法是由电子探针分析值求矿物中Ｆｅ￣（３＋）、Ｆｅ￣（２＋）的新方法。在该方法中，矿物化学式中的阴离子数是唯一已知条件，阳离子数未知，通过本文给出的一系列步骤可以得出实际阳离子数的可能估计。进而求出Ｆｅ＿２Ｏ＿２、ＦｅＯ。该法对Ｆｅ＿２Ｏ＿３、ＦｅＯ的计算结果避免了出现负值，在总体上，该方法的计算结果较其它方法更接近其化学分析值。  相似文献   

豫南中温榴辉岩中角闪石的变质演化   总被引：1，自引：0，他引：1  

王晓燕  崔文元 《岩石矿物学杂志》1996,15(1):65-72,T001

在该区中温榴辉岩的各个演化阶段中，出现了不同成分的角闪石。石榴石环带及其核部的闪石等矿物包囊体记录了前榴辉阶段及其进变质演化的特征。在榴岩阶段晚期，蓝闪石稳定出现，其成分环带反映了压力降低的连续过程；角闪石－斜长石后成合晶为石榴石和绿辉石的退变质产物；退变质后期，钙质闪石大量出现。角闪石的矿物组合及其成分变化，反映了中温榴辉岩的顺时针变质演化过程。  相似文献   

Skarns and Genesis of the Huanggang Fe-Sn Deposit, Inner Mongolia, China   总被引：2，自引：0，他引：2  

Li Juan WANG  Hidehiko SHIMAZAKI  Yoshihide SHIGA 《Resource Geology》2001,51(4):359-376

Abstract: The skarns and genesis were studied of the Huanggang Fe‐Sn deposit and the nearby Sumugou Zn‐Pb deposit in Inner Mongolia, China. In the Huanggang mine, Nos. 1 to 4 Fe ore bodies are arranged along a calcareous horizon from proximal to distal in this order to a granite intrusion named Luotuochangliang, while Sn ore body is situated near another granite intrusion named 204. According to the distance from the granitic intrusions, mineral assemblages in skarns are systematically changed. Garnet is the most predominant skarn mineral throughout the deposit. Hastingsitic amphiboles, however, predominate in the proximal skarns. Fluorite is common in the proximal skarns, while instead calcite is common in the distal skarns. Chlorite is characteristically present only in No. 3 ore body, and chlorite geothermometry gives near 300C for the mineralization of later stage. When garnet crystal shows zonal structure, isotropic andraditic garnet occupies the core, and is surrounded with anisotropic less‐andraditic garnet. The presence of white skarn along the boundary between main skarns and host sedimentary rocks confirms relatively reducing environment prevailing as a whole in the studied area. However, the compositional relation between coexisting garnet and clinopyroxene demonstrates that relatively oxidizing condition was achieved for garnet skarn and magnetite ore in the distal, Nos. 2 to 4 Fe ore bodies and Sumugou deposit, compared to that for garnet skarn in the proximal, No. 1 and Sn ore bodies. Preliminary study on the tin content of garnets in the studied area revealed a certain degree of contribution brought from granitic intrusives since the early stage of skarn formation, irrespective of proximal or distal. Oxygen isotope study on garnet, magnetite, quartz and skarn calcite, as well as hydrogen isotope study on hastingsitic amphibole, demonstrates mainly meteoric water origin for the skarn– and ore‐forming solutions. The occurrence of Sn, W, Mo and F minerals indicates that those elements were mainly supplied to the deposit later than the formation of skarns and iron ores, overlapping to them. These constraints allow to delineate the formation model of the deposit as follows (Fig. 10): At the time of late Jurassic to early Cretaceous, felsic activity occurred in this region as a part of Yanshanian magmatism, and formed granitic intrusions as well as thick volcanic piles on the surface. The circulation of meteoric water was provoked by the heat brought by the intrusions. By this circulation, much amount of iron was extracted from andesites of the Dashizhai Formation, and precipitated as skarns and magnetite ores along calcareous horizons near the bottom of the Huanggangliang Formation. Subsequently, volatile‐rich fluids with Sn, W and Mo were expelled from the solidifying granitic magmas, and precipitated these metals in the pre‐existing skarns and ores.  相似文献   

东秦岭商丹地区蛇绿岩中的角闪石研究   总被引：1，自引：0，他引：1  

白学让  原莲肖 《岩石矿物学杂志》1990,9(2):137-147

东秦岭蛇绿岩主要分布在北秦岭南缘、商丹断裂带以北的狭窄地带,断续逶迤呈带状作近东西向展布。分布于商丹地区的蛇绿岩是东秦岭蛇绿岩带的重要组成部分并具有代表性。 本文着重论述了商丹地区蛇绿岩中广泛分布的主要造岩矿物之一,角闪石的主要特征组份、微量元素、晶胞参数、阳离子占位度等成因矿物学特点。并据此说明了该蛇绿岩中的角闪石属于区域正变质的产物;形成的物质来源具有同源性,原岩为超镁铁质-镁铁质的岩浆岩和火山熔岩;形成的热力学条件基本相同,变质程度为绿帘角闪岩相或角闪岩相,变质温度为610℃左右,压力大于5×10~8Pa。 此外,根据商丹地区蛇绿岩中角闪石成因矿物学特征之相同性所提供的信息表明,东秦岭蛇绿岩带是华北和扬子两个板块俯冲、碰撞的构造边界变质带。  相似文献   

钾-氩和氩-氩定年样品的送样要求及预处理   总被引：11，自引：1，他引：11  

刘玉琳苗国均  黄宝玲 《岩矿测试》2003,22(4):297-299

介绍了K-Ar和Ar-Ar法定年样品的送样要求及实验室预处理程序，样品粒度以250～180μm为宜；用量则视样品的K含量和年龄情况而定，K含量越高、年龄越老，所需样品量越少，多数样品的用量在几十至几百毫克；对于年龄情况不清楚的样品，10～20g手标本或者1～2g合适粒度的样品可以保证用量。全岩样品常受蚀变和捕虏晶的影响，有效的预处理可以在很大程度上消除这些干扰因素。文章还介绍了用稀HNO3消除碳酸盐、1．7mol／L HF消除轻微蚀变的影响以及电磁选剔除捕虏晶的实验过程。  相似文献   

南天山西段古生代火山岩Ar-Ar年龄新资料   总被引：7，自引：0，他引：7  

龚福华  李曰俊  王清华  胡世玲  黄智斌  罗俊成 《高校地质学报》2003,9(3):494-498

根据新近采自中国南天山西段志留-泥盆系乌帕塔尔坎群中的安山岩样品和石炭-二叠纪康克林组上部英安岩角砾样品的全岩Ar-Ar定年测试,乌帕塔尔坎群安山岩的坪年龄为427.70±0.60 Ma,等时年龄为426.96±4.57 Ma; 康克林组上部的英安岩角砾的坪年龄为288.16±0.40 Ma,等时年龄为289.18±2.02 Ma.测试结果为研究中国南天山(西段)古生代造山带的构造体系提供了新的依据.  相似文献   

The Role of Lithospheric Mantle Heterogeneity in the Generation of Plio-Pleistocene Alkali Basaltic Suites from NW Harrat Ash Shaam (Israel)   总被引：4，自引：1，他引：3  

WEINSTEIN  Y.; NAVON  O.; ALTHERR  R.; STEIN  M. 《Journal of Petrology》2006,47(5):1017-1050

Plio-Pleistocene volcanism in the Golan and Galilee (northeasternIsrael) shows systematic variability with time and location:alkali basalts were erupted in the south during the Early Pliocene,whereas enriched basanitic lavas erupted in the north duringthe Late Pliocene (Galilee) and Pleistocene (Golan). The basaltsshow positive correlations in plots of ratios of highly to moderatelyincompatible elements versus the concentration of the highlyincompatible element (e.g. Nb/Zr vs Nb, La/Sm vs La) and indiagrams of REE/HFSE (rare earth elements/high field strengthelements) vs REE concentration (e.g. La/Nb vs La). Some of thesecorrelations are not linear but upward convex. ⁸⁷Sr/⁸⁶Sr ratiosvary between 0·7031 and 0·7034 and correlate negativelywith incompatible element concentrations and positively withRb/Sr ratios. We interpret these observations as an indicationthat the main control on magma composition is binary mixingof melts derived from two end-member mantle source components.Based on the high Sr/Ba ratios and negative Rb anomalies inprimitive mantle normalized trace element diagrams and the moderateslopes of MREE–HREE (middle REE–heavy REE) in chondrite-normalizeddiagrams, we suggest that the source for the alkali basalticend-member was a garnet-bearing amphibole peridotite that hadexperienced partial dehydration. The very high incompatibleelement concentrations, low K content, very low Rb contentsand steep MREE–HREE patterns in the basanites are attributedto derivation from amphibole- and garnet-bearing pyroxeniteveins. It is suggested that the veins were produced via partialmelting of amphibole peridotites, followed by complete solidificationand dehydration that effectively removed Rb and K. The requirementfor the presence of amphibole limits both sources to lithosphericdepths. The spatial geochemical variability of the basalts indicatesthat the lithosphere beneath the region is heterogeneous, composedof vein-rich and vein-poor domains. The relatively uniform ¹⁴³Nd/¹⁴⁴Nd(Nd = 4·0–5·2) suggests that the two mantlesources were formed by dehydration and partial melting of anoriginally isotopically uniform reservoir, probably as a resultof a Paleozoic thermal event. KEY WORDS: basanites; lithospheric heterogeneity; magma mixing; amphibole peridotite; pyroxenites  相似文献   

青海南部杂多地区超镁铁质-镁铁质岩石的特征及Ar—Ar定年   总被引：7，自引：0，他引：7  

王毅智祁生胜  安守文许长青 《地质通报》2007,26(6):68-674

通过野外地质研究和室内岩相学、岩石地球化学研究,在位于青藏高原中部的青海杂多地区的双湖-澜沧江结合带中发现了一套超镁铁质岩、镁铁质岩。该超镁铁质岩、镁铁质岩沿北西—南东向区域构造线多呈岩脉状侵入在早石炭世杂多群中,局部呈构造透镜体分布在断裂带中或呈包体分布在白垩纪花岗岩中,出露规模不大,局部侵入体具有层状侵入杂岩体的特征。主要岩石类型为辉石橄榄岩、辉长岩、辉长辉绿岩,岩石地球化学具高Ti、Fe、Al、Ga和LREE中等富集的特征。橄榄岩中角闪石的~(40)Ar/~(39)Ar同位素测年得到275.3Ma±1.9Ma的坪年龄,表明这套超镁铁—镁铁质岩石可能为早、中二叠世弧后盆地拉张的产物。  相似文献   

Pre-eruptive and syn-eruptive conditions in the Black Butte, California dacite: Insight into crystallization kinetics in a silicic magma system     

Molly C. McCanta  Malcolm J. Rutherford  Julia E. Hammer 《Journal of Volcanology and Geothermal Research》2007,160(3-4):263-284

A series of experiments and petrographic analyses have been run to determine the pre-eruption phase equilibria and ascent dynamics of dacitic lavas composing Black Butte, a dome complex on the flank of Mount Shasta, California. Major and trace element analyses indicate that the Black Butte magma shared a common parent with contemporaneously erupted magmas at the Shasta summit. The Black Butte lava phenocryst phase assemblage (20 v.%) consists of amphibole, plagioclase (core An_77.5), and Fe–Ti oxides in a fine-grained (< 0.5 mm) groundmass of plagioclase, pyroxene, Fe–Ti oxides, amphibole, and cristobalite. The phenocryst assemblage and crystal compositions are reproduced experimentally between 890 °C and 910 °C, ≥ 300 MPa, X_H2O = 1, and oxygen fugacity = NNO + 1. This study has quantified the extent of three crystallization processes occurring in the Black Butte dacite that can be used to discern ascent processes. Magma ascent rate was quantified using the widths of amphibole breakdown rims in natural samples, using an experimental calibration of rim development in a similar magma at relevant conditions. The majority of rims are 34 ± 10 μm thick, suggesting a time-integrated magma ascent rate of 0.004–0.006 m/s among all four dome lobes. This is comparable to values for effusive samples from the 1980 Mount St. Helens eruption and slightly faster than those estimated at Montserrat. A gap between the compositions of plagioclase phenocryst cores and microlites suggests that while phenocryst growth was continuous throughout ascent, microlite formation did not occur until significantly into ascent. The duration of crystallization is estimated using the magma reservoir depth and ascent rate, as determined from phase equilibria and amphibole rim widths, respectively. Textural analysis of the natural plagioclase crystals yields maximum growth rates of plagioclase phenocryst rims and groundmass microlites of 8.7 × 10^− 8 and 2.5 × 10^− 8 mm/s, respectively. These rates are comparable to values determined from time-sequenced samples of dacite erupted effusively from Mount St. Helens during 1980 and indicate that syneruptive crystallization processes were important during the Black Butte eruptive cycle.  相似文献   

新疆东天山剪切带型金矿床时代研究   总被引：23，自引：5，他引：23  

陈文 张彦秦克章  王清利王义天 刘新宇 《岩石学报》2007,23(8):2007-2016

东天山造山带中部的秋格明塔什-黄山巨型韧性剪切带内三个典型的剪切带型金矿床——康古尔金矿床、红石金矿床和红山金矿床的同位素年代学研究表明,金矿床成矿作用和剪切带后期的走滑剪切变形作用在时间上具有强烈的耦合关系。秋格明塔什-黄山韧性剪切带剪切变形作用主活动期的时代为262.9～242.8Ma,而剪切带型金矿床金成矿作用发生在261.0～246.5Ma 之间,恰好落在剪切变形作用主活动期的时代范围之内。这种强烈的耦合关系证明了秋格明塔什-黄山韧性剪切带晚期的右行走滑剪切变形作用才是剪切带内一系列金矿床成矿作用的主因。金成矿和右行走滑剪切变形之间的时间耦合关系在不同部位还有不同的表现。在剪切带中-西段的康古尔地区,快速抬升发生在261.5～262.9Ma,而康古尔金矿床主成矿期时代范围是261.0～252.5Ma,可以看出,康古尔金矿床成矿作用刚好发生于剪切带中-西段快速抬升之后。在剪切带东段,快速抬升发生在247.1～246.9Ma 期间,位于该剪切带东段北外带的红山金矿床主成矿期的年龄范围是246.9～246.5Ma,表明该金矿也是在剪切带东段快速抬升冷却之后形成的。金矿石 Ar-Ar 同位素年代学研究未能得到可靠的和早期韧性推覆剪切变形事件相对应的年龄,推测在晚石炭世—早二叠世发生的韧性推覆剪切变形事件可能仅导致了包括金在内的金属元素的初步富集,但由于高温不利于金属元素沉淀和挤压环境不易存在容矿空间等不利因素的影响,导致此阶段并没有形成有工业开采价值的金矿床。只是到了华力西晚期—印支早期,在原韧性推覆剪切带内发生了走滑剪切变形活动,并产生了快速抬升冷却降温到350℃后,在地体缓慢冷却阶段,在脆-韧性剪切带内才有足够的空间和时间形成金矿床。  相似文献